Probing the 5f electrons in a plutonyl(VI) cluster complex

Roy Copping; Catherine Talbot-Eeckelaers; David Collison; Madeleine Helliwell; Andrew J. Gaunt; Iain May; Sean D. Reilly; Brian L. Scott; Ross D. McDonald; Oscar A. Valenzula; Chris J. Jones; Mark J. Sarsfield

doi:10.1039/B908648J

Probing the 5f electrons in a plutonyl(vi)cluster complex†

Roy Copping,^a Catherine Talbot-Eeckelaers,^a David Collison,^b Madeleine Helliwell,^b Andrew J. Gaunt,^c Iain May,*^c Sean D. Reilly,^c Brian L. Scott,^d Ross D. McDonald,^d Oscar A. Valenzula,^de Chris J. Jones^f and Mark J. Sarsfield^f

Author affiliations

* Corresponding authors

^a Centre for Radiochemistry Research, School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

^b School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

^c Chemistry–Inorganic, Isotope and Actinide Chemistry (C-IIAC), Los Alamos National Laboratory, Mail Stop J-514, Los Alamos, NM, USA
E-mail: iainmay@lanl.gov
Fax: +1 505 667 9905
Tel: +1 505 667 8643

^d Materials and Physics Applications, Los Alamos National Laboratory, Mail Stop J-514, Los Alamos, NM, USA

^e Centro de Investigación en Materiales Avanzados S.C. Miguel de Cervantes 120, Complejo Industrial Chihuahua, Chihuahua, Chih, México

^f The UK National Nuclear Laboratory, Central Laboratory, Sellafield, Seascale, Cumbria, UK

Abstract

We report the structural, spectroscopic and preliminary magnetic characterisation of a tri-metallic plutonyl(VI) polyoxometalate complex, K₁₁[K₃(PuO₂)₃(GeW₉O₃₄)₂]·12H₂O.

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Probing the 5f electrons in a plutonyl(vi)cluster complex†

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Probing the 5f electrons in a plutonyl(VI) cluster complex

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