Neutral ligand induced methane elimination from rare-earth metal tetramethylaluminates up to the six-coordinate carbide state†
Abstract
The reaction of 1,3,5-trimethyl-1,3,5-triazacyclohexane (TMTAC) with [La{Al(CH3)4}3] resulted in C–H
* Corresponding authors
a
Universität Bielefeld, Fakultät für Chemie, Anorganische Chemie und Strukturchemie Universitätsstraße 25, Bielefeld, Germany
E-mail:
mitzel@uni-bielefeld.de
Fax: +49 (0)521 106-6026
Tel: +49 (0) 521 106-6163
b International Graduate School of Chemistry, Universität Münster, Corrensstraße 30, Münster, Germany
The reaction of 1,3,5-trimethyl-1,3,5-triazacyclohexane (TMTAC) with [La{Al(CH3)4}3] resulted in C–H
A. Venugopal, I. Kamps, D. Bojer, R. J. F. Berger, A. Mix, A. Willner, B. Neumann, H. Stammler and N. W. Mitzel, Dalton Trans., 2009, 5755 DOI: 10.1039/B905271B
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