Issue 26, 2009
From the journal:

Dalton Transactions

A planar Cu2+ (S = 1/2) kagomé network pillared by 1,2-bis(4-pyridyl) ethane with interesting magnetic properties†

Prakash Kanoo,a   C. Madhu,a   Golam Mostafa,b   Tapas Kumar Maji,*a   A. Sundaresan,a   Swapan K. Patic  and  C. N. R. Raoa  

* Corresponding authors

a Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India
E-mail: tmaji@jncasr.ac.in
Fax: (+91) 80 2208 2766
Tel: (+91) 80 2208 2826

b Department of Physics, Jadavpur University, Jadavpur, Kolkata, India

c Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, India

Abstract

The reaction of Cu(ClO4)2·6H2O and 1,2-bis(4-pyridyl)ethane (bpe) in basic aqueous solution yields a 3D compound, {[Cu3(CO3)2(bpe)3]·2ClO4}n (1) through the atmospheric fixation of CO2 composing Cu(CO3) kagomé layers pillared by the bpe linker that exhibit weak antiferromagnetic interaction in the kagomé layer and interlayer ferromagnetic coupling at low temperature.

Graphical abstract: A planar Cu2+ (S = 1/2) kagomé network pillared by 1,2-bis(4-pyridyl) ethane with interesting magnetic properties

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Article information

DOI
https://doi.org/10.1039/B905229A
Article type
Communication
Submitted
16 Mar 2009
Accepted
20 Mar 2009
First published
31 Mar 2009

Dalton Trans., 2009, 5062-5064

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A planar Cu2+ (S = 1/2) kagomé network pillared by 1,2-bis(4-pyridyl) ethane with interesting magnetic properties

P. Kanoo, C. Madhu, G. Mostafa, T. K. Maji, A. Sundaresan, S. K. Pati and C. N. R. Rao, Dalton Trans., 2009, 5062 DOI: 10.1039/B905229A

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