Issue 13, 2009
From the journal:

Dalton Transactions

A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster†

Hidetaka Yuge,a   Shin-ichiro Asahia  and  T. Ken Miyamoto*a  

* Corresponding authors

a Department of Chemistry, School of Science, Kitasato University, Kitasato, Sagamihara, Kanagawa, Japan
E-mail: orgnmtl@kitasato-u.ac.jp
Fax: +81 42 778 9953
Tel: +81 42 778 7980

Abstract

Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru3O(OAc)5(Cl)(4-methylpyridine)2(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.

Graphical abstract: A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster

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Article information

DOI
https://doi.org/10.1039/B901050P
Article type
Communication
Submitted
16 Jan 2009
Accepted
04 Feb 2009
First published
12 Feb 2009

Dalton Trans., 2009, 2287-2289

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A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster

H. Yuge, S. Asahi and T. K. Miyamoto, Dalton Trans., 2009, 2287 DOI: 10.1039/B901050P

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