Issue 5, 2009
From the journal:

Dalton Transactions

Ionothermal synthesis of two novel metal organophosphonates†

Peter J. Byrne,*a   David S. Wragg,a   John E. Warrenb  and  Russell E. Morris*a  

* Corresponding authors

a EaStChem School of Chemistry, University of St. Andrews, Purdie Building, St. Andrews, UK
E-mail: rem1@st-and.ac.uk
Fax: +44 1334 463818
Tel: +44 1334 463808

b Synchrotron Radiation Source, Daresbury Laboratory, Daresbury, Warrington, UK

Abstract

Two novel metal phosphonates, Al5F(C4H9PO3)6(OH)2(C4N2H6)21 and Ga4F2(C4H9PO3)8H5·(C7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered.

Graphical abstract: Ionothermal synthesis of two novel metal organophosphonates

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Article information

DOI
https://doi.org/10.1039/B813731E
Article type
Paper
Submitted
07 Aug 2008
Accepted
03 Nov 2008
First published
01 Dec 2008

Dalton Trans., 2009, 795-799

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Ionothermal synthesis of two novel metal organophosphonates

P. J. Byrne, D. S. Wragg, J. E. Warren and R. E. Morris, Dalton Trans., 2009, 795 DOI: 10.1039/B813731E

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