Issue 10, 2009
From the journal:

CrystEngComm

Crystal structure of (RBzPy)n[Ni(4-pedt)2] salts engineering by pyridine ring arrangements

Sandra Rabaça,a   Dulce Belo,a   Ana Cláudia Cerdeira,a   Sandra Isabel Godinho Dias,a   Moritz Berkemeier Castelo Branco,a   Laura Cristina Jesus Pereira,a   Isabel Cordeiro Santos,a   Marc Fourmiguéb  and  Manuel Almeida*a  

* Corresponding authors

a Dept. Química, Instituto Tecnologico e Nuclear/CFMCUL, Sacavém, Portugal
E-mail: malmeida@itn.pt
Fax: +351219941455
Tel: +351219946171

b Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes I, Campus de Beaulieu, Rennes, France

Abstract

Two new salts (p-NO2BzPy)2 [Ni(4-pedt)2] and p-BrBzPy [Ni(4-pedt)2] [BzPy=benzylpyridinium, 4-pedt = 1-(pyridine-4-yl)- ethylene-1,2-dithiolate] were prepared and characterized by X-ray diffraction and magnetic measurements. The paramagnetic salt p-BrBzPy [Ni(4-pedt)2] displays strong pair antiferromagnetic interactions.

Graphical abstract: Crystal structure of (RBzPy)n[Ni(4-pedt)2] salts engineering by pyridine ring arrangements

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Article information

DOI
https://doi.org/10.1039/B906594F
Article type
Paper
Submitted
02 Apr 2009
Accepted
09 Jul 2009
First published
31 Jul 2009

CrystEngComm, 2009,11, 2154-2159

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Crystal structure of (RBzPy)n[Ni(4-pedt)2] salts engineering by pyridine ring arrangements

S. Rabaça, D. Belo, A. Cláudia Cerdeira, S. Isabel Godinho Dias, M. Berkemeier Castelo Branco, L. Cristina Jesus Pereira, I. Cordeiro Santos, M. Fourmigué and M. Almeida, CrystEngComm, 2009, 11, 2154 DOI: 10.1039/B906594F

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