Issue 5, 2009
From the journal:

CrystEngComm

Hierarchical halogen bonding induces polymorphism†

Kari Raatikainena  and  Kari Rissanen*a  

* Corresponding authors

a Nanoscience Center, Department of Chemistry, University of Jyväskylä, University of Jyväskylä, P.O.Box 35, Finland
E-mail: Kari.Rissanen@jyu.fi
Fax: +358-14-2602651
Tel: +358-14-2602672

Abstract

Co-crystals of 1-iodo-3,5-dinitrobenzene and 1,4-diazabicyclo[2.2.2]octane manifest either two strong or one strong and one weak intermolecular 2 : 1 halogen bond (XB) motifs in polymorphic structures I and II, respectively, whereas weaker XB-donor 4,4-bipyridine just forms 1 : 1 structure III with one strong halogen bond.

Graphical abstract: Hierarchical halogen bonding induces polymorphism

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Article information

DOI
https://doi.org/10.1039/B821085N
Article type
Communication
Submitted
25 Nov 2008
Accepted
08 Jan 2009
First published
03 Feb 2009

CrystEngComm, 2009,11, 750-752

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Hierarchical halogen bonding induces polymorphism

K. Raatikainen and K. Rissanen, CrystEngComm, 2009, 11, 750 DOI: 10.1039/B821085N

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