Issue 48, 2008
From the journal:

Dalton Transactions

Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure†

Caroline E. Knapp,a   Claire J. Carmalt,*a   Paul F. McMillan,a   Derek A. Wann,b   Heather E. Robertsonb  and  David W. H. Rankin*b  

* Corresponding authors

a Materials Chemistry Centre, Department of Chemistry, University College London, 20 Gordon Street, London, UK
E-mail: c.j.carmalt@ucl.ac.uk

b School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: d.w.h.rankin@ed.ac.uk

Abstract

The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.

Graphical abstract: Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

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Article information

DOI
https://doi.org/10.1039/B817893N
Article type
Communication
Submitted
10 Oct 2008
Accepted
20 Oct 2008
First published
30 Oct 2008

Dalton Trans., 2008, 6880-6882

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Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure

C. E. Knapp, C. J. Carmalt, P. F. McMillan, D. A. Wann, H. E. Robertson and D. W. H. Rankin, Dalton Trans., 2008, 6880 DOI: 10.1039/B817893N

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