Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−

Haralampos N. Miras; Daniel J. Stone; Eric J. L. McInnes; Raphael G. Raptis; Peter Baran; George I. Chilas; Michael P. Sigalas; Themistoklis A. Kabanos; Leroy Cronin

doi:10.1039/B811279G

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Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo₁₁V₇}: [Mo^VI₁₁V^V₅V^IV₂O₅₂(μ₉-SO₃)]⁷⁻†

Haralampos N. Miras,^a Daniel J. Stone,^b Eric J. L. McInnes,*^b Raphael G. Raptis,^c Peter Baran,^c George I. Chilas,^d Michael P. Sigalas,^e Themistoklis A. Kabanos*^d and Leroy Cronin*^a

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* Corresponding authors

^a WestCHEM, Department of Chemistry, The University of Glasgow, Glasgow, Scotland, UK
E-mail: L.Cronin@chem.gla.ac.uk
Web: http://www.chem.gla.ac.uk/staff/lee
Fax: +44 141 330 4888

^b EPSRC c.w. EPR Centre, School of Chemistry, University of Manchester, Manchester, UK
E-mail: eric.mcinnes@manchester.ac.uk

^c Department of Chemistry, University of Puerto Rico, Río Piedras, PO San Juan, Puerto Rico

^d Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, Greece
E-mail: tkampano@cc.uoi.gr
Fax: +30 651 44831

^e Department of Chemistry, Laboratory of Applied Quantum Chemistry, Aristotle University of Thessaloniki, Greece

Abstract

A polyoxomolybdenum/vanadium-sulfite {M₁₈} cluster-based compound, [Mo^VI₁₁V^V₅V^IV₂O₅₂(μ₉-SO₃)]⁷⁻, is reported that exhibits a unique structural motif, arising from the incorporation of five V^V and two V^IV ions into a {M₁₈} cluster framework templated by SO₃²⁻; this cluster compostion was first identified using cryospray mass spectrometry.

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Article information

DOI: https://doi.org/10.1039/B811279G
Article type: Communication
Submitted: 02 Jul 2008
Accepted: 05 Aug 2008
First published: 15 Sep 2008

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Chem. Commun., 2008, 4703-4705

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Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo₁₁V₇}: [Mo^VI₁₁V^V₅V^IV₂O₅₂(μ₉-SO₃)]⁷⁻

H. N. Miras, D. J. Stone, E. J. L. McInnes, R. G. Raptis, P. Baran, G. I. Chilas, M. P. Sigalas, T. A. Kabanos and L. Cronin, Chem. Commun., 2008, 4703 DOI: 10.1039/B811279G

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