Issue 20, 2008
From the journal:

Organic & Biomolecular Chemistry

Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes†

Hanne Therese Bonge,a   Benjamin Pinteaa  and  Tore Hansen*a  

* Corresponding authors

a University of Oslo, Department of Chemistry, Sem Sælands vei 26, 0315 Oslo, Norway
E-mail: torehans@kjemi.uio.no
Fax: +47 22855386
Tel: +47 22855441

Abstract

Halogenated analogues of ethyl diazoacetate are synthesised by a novel and highly efficient procedure and give halocyclopropanes in good to excellent yields when exposed to a Rh(II) catalyst in the presence of alkenes.

Graphical abstract: Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes

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Article information

DOI
https://doi.org/10.1039/B814374A
Article type
Communication
Submitted
18 Aug 2008
Accepted
20 Aug 2008
First published
10 Sep 2008

Org. Biomol. Chem., 2008,6, 3670-3672

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Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes

H. T. Bonge, B. Pintea and T. Hansen, Org. Biomol. Chem., 2008, 6, 3670 DOI: 10.1039/B814374A

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