Issue 30, 2008
From the journal:

Dalton Transactions

The first metal–organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties†

Da-Wei Fu,a   Wen Zhang*a  and  Ren-Gen Xiong*ab  

* Corresponding authors

a Ordered Matter Science Research Center, Southeast University, Nanjing, P. R. China
E-mail: zhangwen@seu.edu.cn

b Coordination Chemistry Institute, Nanjing University, Nanjing, P. R. China
E-mail: xiongrg@seu.edu.cn
Fax: +86-25-52090626
Tel: +86-25-52090626

Abstract

Hydrothermal reaction of H-Imazethapyr (2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-ethyl-3-pyridinecarboxylic acid) with Cd(ClO4)2·6H2O offers a diamond-like MOF 1Cd(Imazethapyr)2 in which it crystallizes in a non-centrosymmetric space group (Fdd2) belonging to polar point group (C2v). MOF 1 displays a strong SHG response, and good ferroelectric and piezoelectric properties.

Graphical abstract: The first metal–organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties

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Article information

DOI
https://doi.org/10.1039/B806255B
Article type
Communication
Submitted
14 Apr 2008
Accepted
12 May 2008
First published
03 Jun 2008

Dalton Trans., 2008, 3946-3948

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The first metal–organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties

D. Fu, W. Zhang and R. Xiong, Dalton Trans., 2008, 3946 DOI: 10.1039/B806255B

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