Novel octanuclear copper(I) metallomacrocycles and their transformation into hexanuclear 2-dimensional grids of copper(I) coordination polymers containing cyclodiphosphazanes, [(μ-NtBuP)2(NC4H8X)2] (X = NMe, O)

D. Suresh; Maravanji S. Balakrishna; Joel T. Mague

doi:10.1039/B804311F

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Novel octanuclear copper(i) metallomacrocycles and their transformation into hexanuclear 2-dimensional grids of copper(i) coordination polymers containing cyclodiphosphazanes, [(μ-N^tBuP)₂(NC₄H₈X)₂] (X = NMe, O)†

D. Suresh,^a Maravanji S. Balakrishna*^a and Joel T. Mague^b

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* Corresponding authors

^a Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, India
E-mail: krishna@chem.iitb.ac.in
Fax: 91-22-2576-7152

^b Department of Chemistry, Tulane University, New Orleans, LA, USA

Abstract

Novel octanuclear copper(I) macrocyclic complexes and hexanuclear 2-dimensional grid-like polymers containing [P(μ-NR)]₂ scaffold in which the anionic moieties are trapped inside the cationic macrocyclic cavities are reported.

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Article information

DOI: https://doi.org/10.1039/B804311F
Article type: Communication
Submitted: 12 Mar 2008
Accepted: 03 Apr 2008
First published: 21 Apr 2008

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Dalton Trans., 2008, 3272-3274

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Novel octanuclear copper(I) metallomacrocycles and their transformation into hexanuclear 2-dimensional grids of copper(I) coordination polymers containing cyclodiphosphazanes, [(μ-N^tBuP)₂(NC₄H₈X)₂] (X = NMe, O)

D. Suresh, M. S. Balakrishna and J. T. Mague, Dalton Trans., 2008, 3272 DOI: 10.1039/B804311F

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Dalton Transactions