A double [2 + 2] reaction was shown to occur in a crystal to crystal manner in an O–H⋯N hydrogen-bonded co-crystal and was found to occur in a stepwise manner, i.e. one site reacts at a time.
![Graphical abstract: Stepwise dimerization of double [2 + 2] reaction in the co-crystals of 1,5-bis(4-pyridyl)-1,4-pentadiene-3-one and phloroglucinol: a single-crystal to single-crystal transformation](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B813721H&imageInfo.ImageIdentifier.Year=2008)
R. Santra and K. Biradha, CrystEngComm, 2008, 10, 1524 DOI: 10.1039/B813721H
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