A novel nonadecanuclear silver double cage was isolated, in which a square antiprism and a pentacapped pentagonal prism templated by a chloride ion share a tetragonal face to form a snowman-like cluster that is held together by bridging alkynyl groups and trifluoroacetates.
S. Bian and Q. Wang, Chem. Commun., 2008, 5586 DOI: 10.1039/B812451E
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