Issue 43, 2008
From the journal:

Chemical Communications

Tandem conjugate addition–elimination reaction promoted by chiral pyrrolidinyl sulfonamide (CPS)†‡

Junye Xu,a   Xiao Fu,a   Ruijuan Low,a   Yong-Peng Goh,a   Zhiyong Jianga  and  Choon-Hong Tana  

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: chmtanch@nus.edu.sg
Tel: +65-65162845

Abstract

Chiral pyrrolidinyl sulfonamides have been found to promote the conjugate addition–elimination reaction between activated allylic bromides and 1,3-dicarbonyl compounds with high enantioselectivities and the highly functionalised products can be used to generate a variety of interesting enantiomerically pure compounds via simple transformations.

Graphical abstract: Tandem conjugate addition–elimination reaction promoted by chiral pyrrolidinyl sulfonamide (CPS)

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Article information

DOI
https://doi.org/10.1039/B810905M
Article type
Communication
Submitted
26 Jun 2008
Accepted
22 Aug 2008
First published
24 Sep 2008

Chem. Commun., 2008, 5526-5528

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Tandem conjugate addition–elimination reaction promoted by chiral pyrrolidinyl sulfonamide (CPS)

J. Xu, X. Fu, R. Low, Y. Goh, Z. Jiang and C. Tan, Chem. Commun., 2008, 5526 DOI: 10.1039/B810905M

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