Issue 28, 2008

Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides.

Graphical abstract: Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

Supplementary files

Article information

Article type
Communication
Submitted
25 Apr 2008
Accepted
02 May 2008
First published
10 Jun 2008

Chem. Commun., 2008, 3311-3313

Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

S. R. Waetzig and J. A. Tunge, Chem. Commun., 2008, 3311 DOI: 10.1039/B806949B

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