Issue 4, 2008
From the journal:

Chemical Communications

Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials†

Leonardo Apostolico,a   Holger Braunschweig,*a   Andrew G. Crawford,b   Thomas Herbsta  and  Daniela Raisa  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität, Am Hubland, Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: (+49)931-888-4623
Tel: (+49)931-888-5260

b Department of Chemistry, University Science Laboratories, South Road, Durham, UK

Abstract

The first catalytic application of the Group VI metal borylene complexes [(CO)5M[double bond, length as m-dash]BN(SiMe3)2] involves the demercuration reaction of bis(alkynyl)mercurials, [Hg(C[triple bond, length as m-dash]CR)2], with formation of a series of buta-1,3-diynes.

Graphical abstract: Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

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Article information

DOI
https://doi.org/10.1039/B715597B
Article type
Communication
Submitted
10 Oct 2007
Accepted
12 Nov 2007
First published
15 Nov 2007

Chem. Commun., 2008, 497-498

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Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

L. Apostolico, H. Braunschweig, A. G. Crawford, T. Herbst and D. Rais, Chem. Commun., 2008, 497 DOI: 10.1039/B715597B

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