Core-crosslinked block copolymer nanorods as templates for grafting [SiMo12O40]4– Keggin ions

Ram Sai Yelamanchili; Andreas Walther; Axel H. E. Müller; Josef Breu

doi:10.1039/B714435K

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Core-crosslinked block copolymernanorods as templates for grafting [SiMo₁₂O₄₀]^4– Keggin ions†‡

Ram Sai Yelamanchili,^a Andreas Walther,^b Axel H. E. Müller*^b and Josef Breu*^a

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* Corresponding authors

^a Department of Inorganic Chemistry I, University of Bayreuth, Bayreuth, Germany
E-mail: josef.breu@uni-bayreuth.de
Fax: +49 921552788
Tel: +49 921552530

^b Department of Macromolecular Chemistry II, University of Bayreuth, Bayreuth, Germany
E-mail: axel.mueller@uni-bayreuth.de
Fax: +49 921553393
Tel: +49 921553399

Abstract

Core-crosslinked PB-P2VP block copolymer nanorods are used as templates for the synthesis of Keggin-type heteropolyoxometalate (POM) nanostructures by grafting [SiMo₁₂O₄₀]^4– Keggin ions on the template.

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Supplementary files

Experimental details, TEM, SEM, and XRD PDF (2485K)

Article information

DOI: https://doi.org/10.1039/B714435K
Article type: Communication
Submitted: 18 Sep 2007
Accepted: 22 Nov 2007
First published: 07 Dec 2007

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Chem. Commun., 2008, 489-491

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Core-crosslinked block copolymer nanorods as templates for grafting [SiMo₁₂O₄₀]^4– Keggin ions

R. S. Yelamanchili, A. Walther, A. H. E. Müller and J. Breu, Chem. Commun., 2008, 489 DOI: 10.1039/B714435K

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