Issue 2, 2008
From the journal:

Chemical Communications

Synthesis and reactions of β-diketiminato divanadium(i) inverted-sandwich complexes†

Yi-Chou Tsai,*a   Po-Yang Wang,a   Kuan-Ming Lin,a   Shin-An Chenb  and  Jin-Ming Chenb  

* Corresponding authors

a Department of Chemistry, National Tsing Hua University, Taiwan, ROC
E-mail: yictsai@mx.nthu.edu.tw
Fax: +886 3-5711082
Tel: +886 3-5718232

b National Synchrotron Radiation Research Center, Taiwan, ROC

Abstract

Reduction of VCl2(Nacnac) (Nacnac = HC(C(Me)NC6H3-iPr2)2) with KC8 in toluene leads to the formation of a toluene-bridged inverted-sandwich divanadium(I) complex, (µ-η6:η6-C7H8)[V(Nacnac)]2, which behaves as a source of V(Nacnac) and a multi-electron reductant in the two reactions studied in this report.

Graphical abstract: Synthesis and reactions of β-diketiminato divanadium(i) inverted-sandwich complexes

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Article information

DOI
https://doi.org/10.1039/B711816C
Article type
Communication
Submitted
10 Aug 2007
Accepted
11 Oct 2007
First published
19 Oct 2007

Chem. Commun., 2008, 205-207

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Synthesis and reactions of β-diketiminato divanadium(I) inverted-sandwich complexes

Y. Tsai, P. Wang, K. Lin, S. Chen and J. Chen, Chem. Commun., 2008, 205 DOI: 10.1039/B711816C

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