Issue 42, 2007
From the journal:

Dalton Transactions

A novel tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide substituents†‡

Steven Kealey,a   Nicholas J. Long,*a   Andrew J. P. Whitea  and  Antony D. Geeab  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: n.long@imperial.ac.uk
Tel: +44 (0)20 7594 5781

b GSK Clinical Imaging Centre, Imperial College London, Hammersmith Hospital, Du Cane Road, London, UK

Abstract

A new tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide moieties appended to the 3-position of the pyrazolyl rings is reported and shown to display varied coordination chemistry from tridentate N2O coordination with thallium to hexadentate N3O3 coordination with europium.

Graphical abstract: A novel tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide substituents

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Article information

DOI
https://doi.org/10.1039/B711121E
Article type
Communication
Submitted
20 Jul 2007
Accepted
14 Sep 2007
First published
20 Sep 2007

Dalton Trans., 2007, 4763-4765

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A novel tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide substituents

S. Kealey, N. J. Long, A. J. P. White and A. D. Gee, Dalton Trans., 2007, 4763 DOI: 10.1039/B711121E

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