Issue 14, 2007
From the journal:

Dalton Transactions

Homoleptic 12-coordinate lanthanoids with η2-nitroso ligands†

Anthony S. R. Chesman,a   David R. Turner,a   Ekaterina I. Izgorodina,a   Stuart R. Batten*a  and  Glen B. Deacon*a  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Australia
E-mail: stuart.batten@sci.monash.edu.au
Fax: +61 (0)3 9905 4597
Tel: +61 (0)3 9905 4606

Abstract

The complexes [Et4N]3[Ln(η2-dcnm)6] (Ln = La, Ce, Nd, Gd, dcnm = dicyanonitrosomethanide) have discrete N, O 12-coordination owing to symmetrical chelation of the nitroso donor groups.

Graphical abstract: Homoleptic 12-coordinate lanthanoids with η2-nitroso ligands

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Article information

DOI
https://doi.org/10.1039/B702473H
Article type
Communication
Submitted
15 Feb 2007
Accepted
16 Feb 2007
First published
27 Feb 2007

Dalton Trans., 2007, 1371-1373

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Homoleptic 12-coordinate lanthanoids with η2-nitroso ligands

A. S. R. Chesman, D. R. Turner, E. I. Izgorodina, S. R. Batten and G. B. Deacon, Dalton Trans., 2007, 1371 DOI: 10.1039/B702473H

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