Chiral channel-like cavity which is tunable via changes in 21-column packing structure

Yoshitane Imai; Kakuhiro Kawaguchi; Katuzo Asai; Tomohiro Sato; Reiko Kuroda; Yoshio Matsubara

doi:10.1039/B705641A

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Chiral channel-like cavity which is tunable via changes in 2₁-column packing structure†

Yoshitane Imai,*^a Kakuhiro Kawaguchi,^a Katuzo Asai,^a Tomohiro Sato,^b Reiko Kuroda*^bc and Yoshio Matsubara*^a

Author affiliations

* Corresponding authors

^a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan
E-mail: (Y.I.) y-imai@apch.kindai.ac.jp, (Y.M.) y-matsu@apch.kindai.ac.jp

^b JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6, Komaba, Meguro-ku, Tokyo, Japan

^c Department of Life Sciences, Graduate School of Arts and Sciences, University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo, Japan
E-mail: (R.K.) ckuroda@mail.ecc.u-tokyo.ac.jp

Abstract

A complex with a chiral channel-like cavity which can incorporate various n-alkyl alcohols and reversibly discharge and adsorb them, was successfully formed by combining chiral 1,2-diphenylethylenediamine ((1S,2S)-1) and biphenylacetic acid (2).

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Article information

DOI: https://doi.org/10.1039/B705641A
Article type: Communication
Submitted: 13 Apr 2007
Accepted: 08 May 2007
First published: 21 May 2007

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CrystEngComm, 2007,9, 467-470

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Chiral channel-like cavity which is tunable via changes in 2₁-column packing structure

Y. Imai, K. Kawaguchi, K. Asai, T. Sato, R. Kuroda and Y. Matsubara, CrystEngComm, 2007, 9, 467 DOI: 10.1039/B705641A

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