Issue 37, 2007
From the journal:

Chemical Communications

Liquids intermediate between “molecular” and “ionic” liquids: Liquid Ion Pairs?†

Kevin J. Fraser,a   Ekaterina I. Izgorodina,a   Maria Forsyth,b   Janet L. Scotta  and  Douglas R. MacFarlane*a  

* Corresponding authors

a School of Chemistry, Monash University, Clayton Vic 3800, Australia

b Department of Materials Engineering, Monash University, Clayton Vic 3800, Australia
E-mail: douglas.macfarlane@sci.monash.edu.au
Fax: +61 3 9905 4597
Tel: +61 3 9905 4540

Abstract

Ionic liquids comprised of tetradecyltrihexyl- and tetrabutyl- phosphonium cations paired with chloride or sulfonyl amide anions exhibit properties that reflect strong ion association, including comparatively low viscosity as well as a degree of volatility, and hence exemplify an interesting intermediate state between true ionic and true molecular liquids.

Graphical abstract: Liquids intermediate between “molecular” and “ionic” liquids: Liquid Ion Pairs?

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Article information

DOI
https://doi.org/10.1039/B710014K
Article type
Communication
Submitted
02 Jul 2007
Accepted
23 Jul 2007
First published
31 Aug 2007

Chem. Commun., 2007, 3817-3819

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Liquids intermediate between “molecular” and “ionic” liquids: Liquid Ion Pairs?

K. J. Fraser, E. I. Izgorodina, M. Forsyth, J. L. Scott and D. R. MacFarlane, Chem. Commun., 2007, 3817 DOI: 10.1039/B710014K

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