Threading molecular square “beads” on a twofold interpenetrated diamondoid skeleton gives a new type of 3D metal–organic polyrotaxane framework with large channels, in which nanosized Keggin anions as guests are encapsulated for the first time.
X. Wang, C. Qin, E. Wang and Z. Su, Chem. Commun., 2007, 4245 DOI: 10.1039/B709563E
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