Issue 35, 2007
From the journal:

Chemical Communications

Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands†

Mikhail V. Barybin,*a   Malcolm H. Chisholm,*b   Nathan J. Patmore,b   Randall E. Robinsona  and  Namrata Singhb  

* Corresponding authors

a Department of Chemistry, The University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas, USA

b Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio, USA
E-mail: Chisholm@chemistry.ohio-state.edu

Abstract

The preparation and molecular structure of a W24+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π–M2δ–ligand π conjugation.

Graphical abstract: Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

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Article information

DOI
https://doi.org/10.1039/B708746B
Article type
Communication
Submitted
12 Jun 2007
Accepted
06 Jul 2007
First published
07 Aug 2007

Chem. Commun., 2007, 3652-3654

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Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

M. V. Barybin, M. H. Chisholm, N. J. Patmore, R. E. Robinson and N. Singh, Chem. Commun., 2007, 3652 DOI: 10.1039/B708746B

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