Bis(permethylpentalene)cerium – another ambiguity in lanthanide oxidation state
Abstract
Ce(η8-C8Me6)2 exists in a valency close to Ce(III) with some Ce(IV) and provides an example of the Kondo effect in a discrete molecule.
* Corresponding authors
a
Chemistry Research Laboratory, Mansfield Rd, Oxford, UK
E-mail:
dermot.ohare@chem.ox.ac.uk
Fax: 44 1865 285131
Tel: 44 1865 285130
b Inorganic Chemistry Laboratory, South Parks Rd, Oxford, UK
c Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
Ce(η8-C8Me6)2 exists in a valency close to Ce(III) with some Ce(IV) and provides an example of the Kondo effect in a discrete molecule.
A. Ashley, G. Balazs, A. Cowley, J. Green, C. H. Booth and D. O'Hare, Chem. Commun., 2007, 1515 DOI: 10.1039/B700303J
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