Issue 23, 2007
From the journal:

Chemical Communications

Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization†‡

Jing Zhang,a   Milan Gembicky,a   Marc Messerschmidta  and  Philip Coppens*a  

* Corresponding authors

a Department of Chemistry, State University of New York at Buffalo, Buffalo, New York, USA
E-mail: coppens@buffalo.edu
Fax: (716)645-6948

Abstract

Intermolecular H-bonding between C[double bond, length as m-dash]O (ketone) and HO (4′-hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3-di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.

Graphical abstract: Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

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Article information

DOI
https://doi.org/10.1039/B700073A
Article type
Communication
Submitted
04 Jan 2007
Accepted
22 Feb 2007
First published
09 Mar 2007

Chem. Commun., 2007, 2399-2401

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Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

J. Zhang, M. Gembicky, M. Messerschmidt and P. Coppens, Chem. Commun., 2007, 2399 DOI: 10.1039/B700073A

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