Issue 7, 2007
From the journal:

Chemical Communications

Enantioselective palladium-catalysed conjugate addition of arylsiloxanes†

Francesca Gini,a   Bart Hessen,a   Ben L. Feringaa  and  Adriaan J. Minnaard*a  

* Corresponding authors

a Stratingh Institute, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: A.J.Minnaard@rug.nl
Fax: +31 503634296
Tel: +31 503634258

Abstract

The complex formed from Pd(CH3CN)4(BF4)2 and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.

Graphical abstract: Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

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Article information

DOI
https://doi.org/10.1039/B616969D
Article type
Communication
Submitted
21 Nov 2006
Accepted
09 Jan 2007
First published
18 Jan 2007

Chem. Commun., 2007, 710-712

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Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

F. Gini, B. Hessen, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2007, 710 DOI: 10.1039/B616969D

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