Issue 10, 2006
From the journal:

New Journal of Chemistry

Solid state synthesis under supramolecular control of a 2D heterotetratopic self-complementary tecton tailored to halogen bonding†‡

Giovanni Marras,a   Pierangelo Metrangolo,*a   Franck Meyer,a   Tullio Pilati,b   Giuseppe Resnati*a  and  Ashwani Vijc  

* Corresponding authors

a NFMLab - DCMIC “G. Natta”, Via L. Mancinelli 7, Via Castelnuovo 7, 22100 Como, Italy, Italy
E-mail: pierangelo.metrangolo@polimi.it, giuseppe.resnati@polimi.it
Web: http://nfmlab.chem.polimi.it
Fax: +39 02 2399 3180
Tel: +39 02 2399 3041 (P. M.), 3032 (G. R.)

b CNR–ISTM, University of Milan, Via C. Golgi 19, 20133 Milan, Italy

c AFRL/PRSP, 10 E. Saturn Blvd., Edwards AFB, USA

Abstract

We describe the synthesis and characterization, by single crystal X-ray analysis, of a 1D heteroditopic self-complementary tecton for halogen bonding. It was designed to also incorporate double bonds and to possess heteropolar π–π stacking groups in order to carefully control its supramolecular organization in the solid state. As a result of this supramolecular control, by UV irradiation in the solid state the compound dimerizes forming a 2D heterotetratopic self-complementary tecton tailored to halogen bonding based self-assembly. This 2D tecton crystallizes clathrating chloroform molecules.

Graphical abstract: Solid state synthesis under supramolecular control of a 2D heterotetratopic self-complementary tecton tailored to halogen bonding

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Article information

DOI
https://doi.org/10.1039/B605958A
Article type
Paper
Submitted
26 Apr 2006
Accepted
21 Jun 2006
First published
31 Jul 2006

New J. Chem., 2006,30, 1397-1402

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Solid state synthesis under supramolecular control of a 2D heterotetratopic self-complementary tecton tailored to halogen bonding

G. Marras, P. Metrangolo, F. Meyer, T. Pilati, G. Resnati and A. Vij, New J. Chem., 2006, 30, 1397 DOI: 10.1039/B605958A

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