Issue 10, 2006
From the journal:

Dalton Transactions

Substituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols†‡

Peter T. Bishop,a   Andrew R. Cowley,b   Jonathan R. Dilworth,*b   Andrew J. Saundersb  and  John G. Woollard-Shoreb  

* Corresponding authors

a Johnson-Matthey Technology Centre, Blounts Court, Sonning Common, Reading, UK

b Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK
E-mail: jon.dilworth@chem.ox.ac.uk
Fax: 01865-272690
Tel: 01865-285151

Abstract

2,4,6-Trialkylbenzenethiols react with [RuCl2(PPh3)3] to give Ru products with the alkyl substituents forming M–C σ bonds, carbene, carbene with a S α-heteroatom, agostic hydrogen interaction or a simple tetrahedral Ru(II) species, depending on the substituent.

Graphical abstract: Substituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols

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Article information

DOI
https://doi.org/10.1039/B515244E
Article type
Communication
Submitted
26 Oct 2005
Accepted
28 Nov 2005
First published
10 Jan 2006

Dalton Trans., 2006, 1267-1270

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Substituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols

P. T. Bishop, A. R. Cowley, J. R. Dilworth, A. J. Saunders and J. G. Woollard-Shore, Dalton Trans., 2006, 1267 DOI: 10.1039/B515244E

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