The appropriate choice of organometallic nucleophile enables the straightforward preparation of different stereoisomers of 2-substituted pyrrolizidinones utilising the rhodium-catalysed 1,4-addition reaction.
J. D. Hargrave, G. Bish and C. G. Frost, Chem. Commun., 2006, 4389 DOI: 10.1039/B610128C
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