Issue 37, 2006

Palladium-catalyzed silylation of alcohols with hexamethyldisilane

Abstract

The combination of hexamethyldisilane and a catalytic amount of [PdCl(η3-C3H5)]2–PPh3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2.

Graphical abstract: Palladium-catalyzed silylation of alcohols with hexamethyldisilane

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2006
Accepted
14 Jul 2006
First published
04 Aug 2006

Chem. Commun., 2006, 3927-3929

Palladium-catalyzed silylation of alcohols with hexamethyldisilane

E. Shirakawa, K. Hironaka, H. Otsuka and T. Hayashi, Chem. Commun., 2006, 3927 DOI: 10.1039/B608958E

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