Issue 32, 2006
From the journal:

Chemical Communications

Carbonyl–metal fragment insertion into eight-vertex [closo-1-CB7H8]−. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n− {M = Fe, Ru (n = 0), Mn, Re (n = 1)}

Andreas Franken,a   Peng Lei,a   Thomas D. McGratha  and  F. Gordon A. Stonea  

a Department of Chemistry and Biochemistry, Baylor University, Waco, Texas, USA
E-mail: gordon_stone@baylor.edu
Fax: +1-254-710-2043
Tel: +1-254-710-4427

Abstract

Insertion of {M(CO)4} fragments (M = Fe, Ru, Mn, Re) into the eight-vertex monocarborane anion [closo-1-CB7H8]− affords ten-vertex metal–dicarbollide complexes.

Graphical abstract: Carbonyl–metal fragment insertion into eight-vertex [closo-1-CB7H8]−. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n− {M = Fe, Ru (n = 0), Mn, Re (n = 1)}

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Article information

DOI
https://doi.org/10.1039/B607768D
Article type
Communication
Submitted
01 Jun 2006
Accepted
12 Jun 2006
First published
05 Jul 2006

Chem. Commun., 2006, 3423-3425

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Carbonyl–metal fragment insertion into eight-vertex [closo-1-CB7H8]−. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n− {M = Fe, Ru (n = 0), Mn, Re (n = 1)}

A. Franken, P. Lei, T. D. McGrath and F. G. A. Stone, Chem. Commun., 2006, 3423 DOI: 10.1039/B607768D

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