Discrete copper(I) clusters with Cu6P6Se6 and Cu6P4Se6 cores

Robert P. Davies; M. Giovanna Martinelli; Andrew J. P. White

doi:10.1039/B605191J

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Discrete copper(i) clusters with Cu₆P₆Se₆ and Cu₆P₄Se₆ cores†

Robert P. Davies,*^a M. Giovanna Martinelli^a and Andrew J. P. White^a

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* Corresponding authors

^a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: r.davies@imperial.ac.uk
Fax: +44 870 1300438
Tel: +44 207 5945754

Abstract

The reactions of chalcogenophosphinites with copper(I) metal salts are shown to yield highly stable, multi-metallic copper–chalcogen based clusters with novel topologies.

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Article information

DOI: https://doi.org/10.1039/B605191J
Article type: Communication
Submitted: 11 Apr 2006
Accepted: 06 Jun 2006
First published: 26 Jun 2006

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Chem. Commun., 2006, 3240-3242

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Discrete copper(I) clusters with Cu₆P₆Se₆ and Cu₆P₄Se₆ cores

R. P. Davies, M. G. Martinelli and A. J. P. White, Chem. Commun., 2006, 3240 DOI: 10.1039/B605191J

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Chemical Communications