Issue 18, 2006
From the journal:

Chemical Communications

A concise synthesis of (−)-centrolobine via a diastereoselective ring rearrangement metathesis–isomerisation sequence

Verena Böhrscha  and  Siegfried Blechert*a  

* Corresponding authors

a TU Berlin – Berlin University of Technology, Institute of Chemistry, Strasse des 17. Juni 115, Sekr. C3, 10623 Berlin, Germany
E-mail: blechert@chem.tu-berlin
Fax: +49 30 314 23619
Tel: +49 30 314 22255

Abstract

A total synthesis of (−)-centrolobine (1) based on a diastereoselective ring rearrangement metathesis–double bond isomerisation sequence and a one-pot cross metathesis–hydrogenation procedure is described.

Graphical abstract: A concise synthesis of (−)-centrolobine via a diastereoselective ring rearrangement metathesis–isomerisation sequence

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Article information

DOI
https://doi.org/10.1039/B602056A
Article type
Communication
Submitted
13 Feb 2006
Accepted
10 Mar 2006
First published
30 Mar 2006

Chem. Commun., 2006, 1968-1970

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A concise synthesis of (−)-centrolobine via a diastereoselective ring rearrangement metathesis–isomerisation sequence

V. Böhrsch and S. Blechert, Chem. Commun., 2006, 1968 DOI: 10.1039/B602056A

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