Issue 16, 2006
From the journal:

Chemical Communications

Controlling the oxidation state of arsenic in cyclic arsenic cations

Gregor Reeskea  and  Alan H. Cowley*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Texas, USA
E-mail: cowley@mail.utexas.edu
Fax: (+1) 512 471 6822
Tel: (+1) 512 471 7484

Abstract

Reduction of AsCl3 with SnCl2, followed by treatment of the “AsCl” with a 1,4-diimine results in electron transfer and formation of an arsenic(III) salt, while treatment of this arsenic(I) reagent or AsI3 with an α,α′-diiminopyridine ligand forms an arsenic(I) salt.

Graphical abstract: Controlling the oxidation state of arsenic in cyclic arsenic cations

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Article information

DOI
https://doi.org/10.1039/B602017H
Article type
Communication
Submitted
10 Feb 2006
Accepted
26 Feb 2006
First published
20 Mar 2006

Chem. Commun., 2006, 1784-1786

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Controlling the oxidation state of arsenic in cyclic arsenic cations

G. Reeske and A. H. Cowley, Chem. Commun., 2006, 1784 DOI: 10.1039/B602017H

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