Issue 17, 2006
From the journal:

Chemical Communications

Comparing a mononuclear Zn(ii) complex with hydrogen bond donors with a dinuclear Zn(ii) complex for catalysing phosphate ester cleavage†

Guoqiang Feng,a   Juan C. Mareque-Rivas*b  and  Nicholas H. Williams*a  

* Corresponding authors

a Centre for Chemical Biology, Department of Chemistry, University of Sheffield, Sheffield, UK
E-mail: N.H.Williams@Sheffield.ac.uk
Fax: 0114 2229346
Tel: 0114 2229469

b School of Chemistry, University of Edinburgh, Edinburgh, UK
E-mail: juan.mareque@ed.ac.uk
Fax: 0131 6504743
Tel: 0131 6504761

Abstract

Introducing ligand based hydrogen bond donors to increase the activity of a mononuclear Zn(II) complex for catalysing phosphate ester cleavage can be a more effective strategy than making the dinuclear analogue.

Graphical abstract: Comparing a mononuclear Zn(ii) complex with hydrogen bond donors with a dinuclear Zn(ii) complex for catalysing phosphate ester cleavage

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Article information

DOI
https://doi.org/10.1039/B514328D
Article type
Communication
Submitted
12 Oct 2005
Accepted
20 Mar 2006
First published
03 Apr 2006

Chem. Commun., 2006, 1845-1847

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Comparing a mononuclear Zn(II) complex with hydrogen bond donors with a dinuclear Zn(II) complex for catalysing phosphate ester cleavage

G. Feng, J. C. Mareque-Rivas and N. H. Williams, Chem. Commun., 2006, 1845 DOI: 10.1039/B514328D

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