Issue 6, 2005
From the journal:

Green Chemistry

Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines

Yue Zhang,a   Kara Forinash,a   Courtney R. Phillipsa  and  Lisa McElwee-White*a  

* Corresponding authors

a Department of Chemistry and Center for Catalysis, University of Florida, Gainesville, FL 32611-7200
E-mail: lmwhite@chem.ufl.edu

Abstract

Biotin methyl ester and related heterocyclic ureas were synthesized by W(CO)6-catalyzed oxidative carbonylation of the corresponding diamines. This procedure provides an alternative to the use of phosgene and phosgene derivatives for formation of the urea moiety.

Graphical abstract: Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines

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Article information

DOI
https://doi.org/10.1039/B500197H
Article type
Paper
Submitted
06 Jan 2005
Accepted
21 Mar 2005
First published
12 Apr 2005

Green Chem., 2005,7, 451-455

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Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines

Y. Zhang, K. Forinash, C. R. Phillips and L. McElwee-White, Green Chem., 2005, 7, 451 DOI: 10.1039/B500197H

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