Issue 15, 2005
From the journal:

Dalton Transactions

Triphosph(iii)azanes to diphosph(iii)azanes; a cracking transformation†

Felipe García,a   Richard A. Kowenicki,*a   Lucía Rieraa  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk
Tel: 0044 1223 763122

Abstract

The reversible interconversion between trimeric [ClPNEt]3 (1) and dimeric [ClPNEt]2 (2) reported here is the first observation of such a thermally induced rearrangement between two cyclophosphazane oligomers; the structure of 1·cis is reported along with NMR studies of its conversion into 2.

Graphical abstract: Triphosph(iii)azanes to diphosph(iii)azanes; a cracking transformation

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Article information

DOI
https://doi.org/10.1039/B505720E
Article type
Communication
Submitted
24 May 2005
Accepted
15 Jun 2005
First published
04 Jul 2005

Dalton Trans., 2005, 2495-2496

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Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation

F. García, R. A. Kowenicki, L. Riera and D. S. Wright, Dalton Trans., 2005, 2495 DOI: 10.1039/B505720E

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