Issue 43, 2005
From the journal:

Chemical Communications

Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines†

Jean-Philippe Ebran,a   Rita G. Hazella  and  Troels Skrydstrup*a  

* Corresponding authors

a Department of Chemistry, University of Aarhus, Langelandsgade 140, Aarhus C, Denmark
E-mail: ts@chem.au.dk
Fax: +45 8619 6199
Tel: +45 8942 3932

Abstract

Pinacol coupling of alkyl dinitrones mediated by SmI2 was achieved in the presence of a proton source allowing the synthesis of cyclic vicinal diamines with good cis-selectivity.

Graphical abstract: Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

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Article information

DOI
https://doi.org/10.1039/B511491H
Article type
Communication
Submitted
11 Aug 2005
Accepted
09 Sep 2005
First published
30 Sep 2005

Chem. Commun., 2005, 5402-5404

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Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

J. Ebran, R. G. Hazell and T. Skrydstrup, Chem. Commun., 2005, 5402 DOI: 10.1039/B511491H

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