Issue 39, 2005
From the journal:

Chemical Communications

Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α,β-unsaturated pyridylsulfones†

Pablo Mauleóna  and  Juan C. Carretero*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco 28049 Madrid, Spain
E-mail: juancarlos.carretero@uam.es
Fax: 91 497 3966
Tel: 91 497 3925

Abstract

The highly enantioselective construction of all-carbon quaternary stereogenic centres via Rh-catalyzed Chiraphos-mediated conjugate addition of alkenylboronic acids to β,β-disubstituted α,β-unsaturated 2-pyridylsulfones is described.

Graphical abstract: Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α,β-unsaturated pyridylsulfones

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Article information

DOI
https://doi.org/10.1039/B508142D
Article type
Communication
Submitted
14 Jun 2005
Accepted
05 Aug 2005
First published
08 Sep 2005

Chem. Commun., 2005, 4961-4963

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Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α,β-unsaturated pyridylsulfones

P. Mauleón and J. C. Carretero, Chem. Commun., 2005, 4961 DOI: 10.1039/B508142D

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