Issue 16, 2005
From the journal:

Chemical Communications

One-pot tandem living radical polymerisation–Huisgens cycloaddition process (“click”) catalysed by N-alkyl-2-pyridylmethanimine/Cu(i)Br complexes†

Giuseppe Mantovani,a   Vincent Ladmiral,a   Lei Taoa  and  David M. Haddleton*a  

* Corresponding authors

a Department of Chemistry, University of Warwick, Coventry, UK
E-mail: D.M.Haddleton@warwick.ac.uk
Fax: +44 24 7652 8267
Tel: +44 24 7652 3256

Abstract

Azide terminally functional poly(methyl methacrylate)s (Mn = 4000–6000, PDI = 1.21–1.28) have been prepared by living radical polymerization and successfully reacted with alkynes in a Huisgen cycloaddition (click) reaction in one pot using the same catalyst for both processes.

Graphical abstract: One-pot tandem living radical polymerisation–Huisgens cycloaddition process (“click”) catalysed by N-alkyl-2-pyridylmethanimine/Cu(i)Br complexes

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Article information

DOI
https://doi.org/10.1039/B500558B
Article type
Communication
Submitted
13 Jan 2005
Accepted
17 Feb 2005
First published
02 Mar 2005

Chem. Commun., 2005, 2089-2091

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One-pot tandem living radical polymerisation–Huisgens cycloaddition process (“click”) catalysed by N-alkyl-2-pyridylmethanimine/Cu(I)Br complexes

G. Mantovani, V. Ladmiral, L. Tao and D. M. Haddleton, Chem. Commun., 2005, 2089 DOI: 10.1039/B500558B

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