Issue 12, 2005
From the journal:

Chemical Communications

Steric engineering of C–F activation with lanthanoid formamidinates

Marcus L. Cole,†a   Glen B. Deacon,a   Peter C. Junk*a  and  Kristina Konstasa  

* Corresponding authors

a School of Chemistry, Monash University, P.O. Box 23, Victoria 3800, Australia
E-mail: peter.junk@sci.monash.edu.au
Fax: +61 (0)3 9905 4597
Tel: +61 (0)3 9905 4570

Abstract

Reaction of lanthanum with Hg(C6F5)2 and bulky N,N′-bis(2,6-diisopropylphenyl)formamidine (HDippForm) in tetrahydrofuran gives [LaF{DippForm}2(THF)] with a rare terminal Ln–F bond, and a high yield of a novel functionalised formamidine, DippForm((CH2)4OC6F4H-o).

Graphical abstract: Steric engineering of C–F activation with lanthanoid formamidinates

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Article information

DOI
https://doi.org/10.1039/B419047E
Article type
Communication
Submitted
21 Dec 2004
Accepted
31 Jan 2005
First published
15 Feb 2005

Chem. Commun., 2005, 1581-1583

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Steric engineering of C–F activation with lanthanoid formamidinates

M. L. Cole, G. B. Deacon, P. C. Junk and K. Konstas, Chem. Commun., 2005, 1581 DOI: 10.1039/B419047E

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