Issue 15, 2005
From the journal:

Chemical Communications

Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide†

Rajshekhar Ghosha  and  Ashoka G. Samuelson*a  

* Corresponding authors

a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India
E-mail: ashoka@ipc.iisc.ernet.in
Fax: 91-80-23601552
Tel: 91-80-22932663

Abstract

The insertion of an isopropoxide ligand of titanium isopropoxide into heterocumulenes gives a product that carries out metathesis at elevated temperatures by undergoing insertion of a second heterocumulene in a head to head fashion, followed by an extrusion reaction.

Graphical abstract: Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B417713D
Article type
Communication
Submitted
25 Nov 2004
Accepted
26 Jan 2005
First published
24 Feb 2005

Chem. Commun., 2005, 2017-2019

Permissions

Request permissions

Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide

R. Ghosh and A. G. Samuelson, Chem. Commun., 2005, 2017 DOI: 10.1039/B417713D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements