Issue 2, 2005
From the journal:

Chemical Communications

The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh→B) (mt = methimazolyl)†

Ian R. Crossley,a   Mark R. St.-J. Foreman,b   Anthony F. Hill,*a   Andrew J. P. Whiteb  and  David J. Williamsb  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, ACT Australia
E-mail: a.hill@anu.edu.au
Fax: +61 2 6125 3216
Tel: +61 2 6125 8577

b Imperial College London, South Kensington, London, UK

Abstract

The reaction of [Rh(C6H5)Cl2(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh→B) the first authentic example of a compound with a rhodium–boron dative bond.

Graphical abstract: The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh→B) (mt = methimazolyl)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B413305F
Article type
Communication
Submitted
01 Sep 2004
Accepted
28 Sep 2004
First published
25 Nov 2004

Chem. Commun., 2005, 221-223

Permissions

Request permissions

The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh→B) (mt = methimazolyl)

I. R. Crossley, M. R. St.-J. Foreman, A. F. Hill, A. J. P. White and D. J. Williams, Chem. Commun., 2005, 221 DOI: 10.1039/B413305F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements