Issue 3, 2005
From the journal:

Chemical Communications

Phosphonium ionic liquids as reaction media for strong bases

Taramatee Ramnial,a   Daisuke D. Inoa  and  Jason A. C. Clyburne*a  

* Corresponding authors

a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, Canada
E-mail: clyburne@sfu.ca

Abstract

Phosphonium ionic liquids are compatible with strong bases; for example, solutions composed of commercially available phenylmagnesium bromide in THF are persistent in tetradecyl(trihexyl)phosphonium chloride for several hours–days: their stability appears to be couched in kinetic terms.

Graphical abstract: Phosphonium ionic liquids as reaction media for strong bases

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Article information

DOI
https://doi.org/10.1039/B411646A
Article type
Communication
Submitted
28 Jul 2004
Accepted
12 Oct 2004
First published
10 Dec 2004

Chem. Commun., 2005, 325-327

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Phosphonium ionic liquids as reaction media for strong bases

T. Ramnial, D. D. Ino and J. A. C. Clyburne, Chem. Commun., 2005, 325 DOI: 10.1039/B411646A

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