Issue 3, 2005
From the journal:

Chemical Communications

Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect†

David B. Amabilino,*a   José-Luis Serranob  and  Jaume Vecianaa  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Catalonia, Spain
E-mail: amabilino@icmab.es
Fax: +34 93 580 5729
Tel: +34 93 580 1853

b Instituto de Ciencia de Materiales de Aragón (CSIC), Universidad de Zaragoza, Zaragoza, Spain
E-mail: joseluis@unizar.es
Fax: +34 976 761209
Tel: +34 976 761209

Abstract

Poly(isocyanide)s prepared by diastereoselective polymerisation of two chiral monomers, which differ only in the presence of a nitro-group adjacent to the stereogenic group, exhibit long range chiral induction, but a surprising influence of a remote substituent on the conformation and stability of the secondary structure in the macromolecules.

Graphical abstract: Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect

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Article information

DOI
https://doi.org/10.1039/B411449C
Article type
Communication
Submitted
26 Jul 2004
Accepted
30 Sep 2004
First published
08 Dec 2004

Chem. Commun., 2005, 322-324

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Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect

D. B. Amabilino, J. Serrano and J. Veciana, Chem. Commun., 2005, 322 DOI: 10.1039/B411449C

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