Issue 9, 2004

Synthetic transition metal phyllosilicates and organic-inorganic related phases

Abstract

We present a brief overview of the first-row transition metal phyllosilicates and their organically functionalised analogues obtained under autogenous pressure conditions. Some structural features of phyllosilicates are first recalled and the magnetic properties of Co2+ and Ni2+ phyllosilicates are described. In the second part, the state-of-the-art in organically functionalised phyllosilicates is reported, including our contributions on the structural and magnetic characterisation. The impetus is to enhance the potential of these new compounds as multi-property materials. Since our interest lies in low-dimensional magnetic properties, divalent transition metal cations are involved in the layered inorganic layers, whereas 3-aminopropyltriethoxysilane is used as the silicon source.

Graphical abstract: Synthetic transition metal phyllosilicates and organic-inorganic related phases

Article information

Article type
Perspective
Submitted
08 Dec 2003
Accepted
30 Mar 2004
First published
10 Aug 2004

New J. Chem., 2004,28, 1073-1082

Synthetic transition metal phyllosilicates and organic-inorganic related phases

M. Richard-Plouet, S. Vilminot and M. Guillot, New J. Chem., 2004, 28, 1073 DOI: 10.1039/B316089K

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