Wiring nanoparticles with redox molecules

Abstract

Gold nanoparticles were used to make electrical contact to redox-active organic molecules. Viologen based dithiols were self-assembled from solution on Au(111) for use as tethers to attach nanoparticles to a conducting substrate. The topography and electrical properties of the resulting films were investigated by STM and STS and the orientation of these linkers was investigated by FTIR. Surface coverage increased with increasing reaction time, resulting in a change of film orientation from a flat to a more upright standing conformation. Gold nanoparticles attached to these self-assembled films were characterised by STM. It was possible to isolate a single redox-active molecule in an alkanethiol matrix and by subsequent attachment of a single gold nanoparticle the electrical properties of single wired molecules could be investigated. This method allowed the measurement of the conductivity of single molecules connecting a nanoparticle to the substrate chemically, thus forming stable electrical contacts at both ends.