Issue 3, 2004
From the journal:

Dalton Transactions

Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

Kuo-Wei Huanga  and  Robert M. Waymouth*a  

* Corresponding authors

a Department of Chemistry, Stanford University, Stanford, CA 94305, USA
E-mail: waymouth@stanford.edu

Abstract

The η1-hydroxylamido half-titanocene complex, CpTiCl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

Graphical abstract: Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

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Article information

DOI
https://doi.org/10.1039/B314027J
Article type
Communication
Submitted
04 Nov 2003
Accepted
05 Jan 2004
First published
14 Jan 2004

Dalton Trans., 2004, 354-356

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Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

K. Huang and R. M. Waymouth, Dalton Trans., 2004, 354 DOI: 10.1039/B314027J

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